Synthesis and Tunable Optical Properties of C,N-Chelated Borate Luminophores Derived from Potassium Acyltrifluoroborates.

A new class of borate luminophores has been synthesized by a simple two-step reaction using potassium acyltrifluoroborates (KATs) as starting materials. The hydrazones obtained from reactions between KATs and 2-hydrazinopyridines followed by a cyclization resulted in the unprecedented formation of C,N-chelated six-membered bora-heterocycles. Under consideration of the results of DFT and TD-DFT calculations, four luminophores based on such bora-heterocycles are designed and synthesized, which exhibit a tunable fluorescence range from blue to red in the solid state. Moreover, one of the luminophores exhibits mechanofluorochromism from blue to yellow/green. As a result of the aforementioned mechanochromism of one of these luminophores, white-color emission was achieved by simply mixing the four luminophores.