Observation of electronic structure replicas in photoemission spectra of graphite upon adsorption of tin phthalocyanine.

Cone-type bands near the center of the surface Brillouin zone were observed in low-energy angle-resolved photoemission spectra of tin phthalocyanine adsorbed on graphite. Simulations in comparison with the experimental data show that the spectral features represent replicas of the electronic structure of graphite near K resulting from high-order momentum transfer processes up to the fourth order owing to the interaction of substrate electrons with the long-range structural order of the adsorbate overlayer. The analysis of time-resolved photoemission data from one of the replicas yields a quantitative and very good agreement with previous studies on the excited carrier dynamics in the Dirac cones of graphite and graphene.