Login / Signup

Communication: Symmetrical quasi-classical analysis of linear optical spectroscopy.

Justin ProvazzaDavid F Coker
Published in: The Journal of chemical physics (2018)
The symmetrical quasi-classical approach for propagation of a many degree of freedom density matrix is explored in the context of computing linear spectra. Calculations on a simple two state model for which exact results are available suggest that the approach gives a qualitative description of peak positions, relative amplitudes, and line broadening. Short time details in the computed dipole autocorrelation function result in exaggerated tails in the spectrum.
Keyphrases