Evidence for a lowest energy 3MLCT excited state in [Fe(tpy)(CN)3].

Sebastian B VittardiRajani Thapa MagarBriana R SchrageChristopher J Ziegler Elena Jakubikova Jeffrey J Rack

Published in: Chemical communications (Cambridge, England) (2021)

Transient absorption data of [FeII(tpy)(CN)3]- reveals spectroscopic signatures indicative of 3MLCT with a ∼10 ps kinetic component. These data are supported by DFT and TD-DFT calculations, which show that excited state ordering is responsive to the number of cyanide ligands on the complex.

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