Reactivity of vinylidene-π-allyl palladium(II) species.

Can LiZhengnan ZhouYuling LiYin-Long Guo Shengming Ma

Published in: Chemical communications (Cambridge, England) (2023)

The reactivity of a new type of organometallic intermediate, vinylidene-π-allyl palladium species, has been demonstrated: the reaction between 4-alken-2-ynyl carbonates and stabilized carbon nucleophiles afforded functionalized 1,2,3,-butatriene compounds in moderate to high yields and excellent regioselectivities.

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