Magneto-Luminescent Two-Dimensional Nanosheets of Gadolinium and Gold Nanocluster Assemblies with Surface Molecular Functionalization for White Light Emission.

We report the formation of photoluminescent two-dimensional (2D) crystalline nanosheet assemblies of gadolinium ions and ligand-stabilized gold nanoclusters (Gd-Au NCs). Transmission electron microscopy, selected area electron diffraction in conjunction with atomic force microscopy, and field-emission scanning electron microscopy analyses substantiated the 2D nature of Gd-Au NC nanosheets. The optical and magnetic properties of the nanosheets were investigated by photoluminescence measurements and vibrating-sample magnetometry analyses. The so-formed crystalline product was further utilized to generate a synchronous tricolor (orange, green, and blue) emission from a single excitation wavelength through an inorganic surface complexation reaction. The independent emissions were tunable after ligand functionalization by acetylsalicylic acid and fluorescein on the Gd-Au NC assembly. Interestingly, the assembled superstructure with augmented quantum yield led to white light emission at λ exc ≈ 325 nm with CIE of (0.34, 0.33) and CRI value of >85 in the liquid phase. Furthermore, the ability to modulate the luminescence properties through the surface complexation of the 2D nanosheets of Au NCs may bring about new avenues toward applications in light-emitting devices, sensing, and biomedical imaging.