Self-Assembly and Fluorescence of Tetracationic Liquid Crystalline Tetraphenylethene.
Jakob KnellesStuart BeardsworthKorinna BaderJohanna R BrucknerAndrea BühlmeyerRobert ForschnerKevin SchweizerWolfgang FreyFrank GiesselmannYann MolardSabine LaschatPublished in: Chemphyschem : a European journal of chemical physics and physical chemistry (2019)
A series of tetraguanidinium tetraphenylethene (TPE) arylsulfonates with different chain lengths was prepared via ionic self-assembly of tetraguanidinium TPE chloride and the respective methyl arylsulfonates. Liquid crystalline properties were studied by differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction. Tetraguanidinium TPE arylsulfonates with chain lengths of C8 -C12 displayed hexagonal columnar mesophases over a broad temperature range, while derivatives with longer chains showed oblique columnar phases. In solution all compounds displayed aggregation-induced emission behaviour. Temperature-dependent luminescence spectra of the bulk phase of the tetraguanidinium TPE arylsulfonate with C14 side chains revealed a strong luminescence both in the solid state and the oblique columnar mesophase. The emission behaviour was rationalized by a unique combination of restriction of intramolecular rotation of the TPE core, Coulomb interaction between the guanidinium cations and π-π interactions of the anionic arylsulfonate moieties.