Rhodium(III)-Catalyzed C-H/N-H Functionalization with Hydrogen Evolution.
Hui XieJi-Jun JiangJun WangPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2020)
A rhodium(III)-catalyzed C-H/N-H bond functionalization of benzimidates with α-chloroaldehydes to afford isoquinolin-3-ol derivatives is reported. No external oxidants are needed in this process, and interestingly, evolution of hydrogen gas is observed.
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