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Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions.

Tatsuya MorofujiTakuma KurokawaYouhei ChitoseChihaya AdachiNaokazu Kano
Published in: Organic & biomolecular chemistry (2022)
In this study, we propose that the trifluoromethylated thermally activated delayed fluorescent molecule 4[Cz(CF 3 ) 2 ]IPN is a versatile organic photocatalyst that can be used for electron-transfer-driven reactions requiring a photocatalyst with high oxidizing power and energy-transfer-driven reactions that require an Ir photocatalyst. 4[Cz(CF 3 ) 2 ]IPN was used in radical reactions via electron transfer and dearomative cycloaddition reactions via energy transfer.
Keyphrases
  • energy transfer
  • electron transfer
  • quantum dots
  • visible light
  • highly efficient
  • cystic fibrosis
  • water soluble