Metastable Hexagonal-Phase Nickel with Ultralow Pt Content for an Efficient Alkaline/Seawater Hydrogen Evolution Reaction.

Hydrogen has been hailed as the core of the world's future energy architecture. It is imperative to develop catalysts with an efficient and sustained hydrogen evolution reaction (HER) to scale up alkaline/seawater electrolysis, yet significant difficulties and challenges, such as the high usage of precious metals, still remain. In this paper, a metastable-phase hexagonal close-packed (hcp) Ni-based catalyst with ultralow Pt content (3.1 at %) was designed, which has excellent catalytic performance in the alkaline/seawater HER. The optimal catalyst offers low overpotentials of 21 and 137 mV at 10 mA cm -2 and remains stable during operation for 100 and 300 h at this current density in 1.0 M KOH and real seawater, respectively. A mechanistic study shows that the metastable-phase Ni acts as an anchor site for OH - , which promotes the dissociation of water and greatly improves the formation rate of H 2 .