Understanding the Role of Paper-Ink Interactions on the Lightfastness of Thermochromic Prints.

Thermochromic inks (TC) have received increasing attention in recent years, particularly in the design and packaging industries. Their stability and durability are crucial for their application. This study highlights the detrimental effects of UV radiation on the lightfastness and reversibility of thermochromic prints. Three commercially available TC inks with different activation temperatures and in different shades were printed on two different substrates, cellulose and polypropylene-based paper. Used inks were vegetable oil-based, mineral oil-based and UV-curable. The degradation of the TC prints was monitored using FTIR and fluorescence spectroscopy. Colorimetric properties were measured before and after exposure to UV radiation. The substrate with a phorus structure exhibited better colour stability, suggesting that the chemical composition and surface properties of the substrate play a crucial role in the overall stability of thermochromic prints. This can be explained by the ink penetration into the printing substrate. The penetration of the ink into the structure (cellulose fibres) protects the ink pigments from the negative effect of the UV radiation. Obtained results suggest that although the initial substrate may appear suitable for printing, its performance after ageing may not be optimal. In addition, the UV curable prints show better light stability than those made of mineral- and vegetable-based inks. In the field of printing technology, understanding the interplay between different printing substrates and inks is critical to achieve high-quality, long-lasting prints.