Ultrasonic Auxiliary Ozone Oxidation-Extraction Desulfurization: A Highly Efficient and Stable Process for Ultra-Deep Desulfurization.
Rui WangKaiqing ZhangIvan V KozhevnikovPublished in: Molecules (Basel, Switzerland) (2022)
For ultra-deep desulfurization of diesel fuel, this study applied the ultrasound-assisted catalytic ozonation process to the dibenzothiophene (DBT) removal process with four Keggin-type heteropolyacids (HPA) as catalysts and acetonitrile as extractant. Through experimental evaluations, H 3 PMo 12 O 40 was found to be the most effective catalyst for the oxidative removal of DBT. Under favorable operating conditions with a temperature of 0 °C, H 3 PMo 12 O 40 dosage of 2.5 wt.% of n -octane, and ultrasonic irradiation, DBT can be effectively removed from simulated diesel. Moreover, the reused catalyst exhibited good catalytic activity in recovery experiments. This desulfurization process has high potential for ultra-deep desulfurization of diesel.