Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex.
Rong-Jia WeiRyohei NakaharaJamie M CameronGraham N NewtonTakuya ShigaHajime SagayamaReiji KumaiYouichi MurakamiH Hiroki OshioPublished in: Dalton transactions (Cambridge, England : 2003) (2018)
A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.