Double intramolecular hydrogen transfer assisted dual emission in a carbazole-embedded porphyrin-like macrocycle.

Arumugan KalaiselvanAswini SpergenIsukapalli Sai Vamsi Krishna Vennapusa Sivaranjana Reddy Sabapathi Gokulnath

Published in: Chemical communications (Cambridge, England) (2021)

The introduction of a pyrrole ring at one of the meso positions of carbazole-based porphyrins lowers the structural symmetry and results in dual emission, which strongly depends on the excitation wavelength and temperature. The origin of dual emission induced by NH-tautomerism is confirmed via photophysical and DFT calculations.

Keyphrases

density functional theory
energy transfer
photodynamic therapy
solid state
molecular docking
metal organic framework