Anti-Biofouling and Water-Stable Balanced Charged Metal Organic Framework-Based Polyelectrolyte Hydrogels for Extracting Uranium from Seawater.

Metal-organic frameworks (MOFs) are diffusely defined as a promising class of porous material for uranium extraction from seawater, but there are still challenges in their stability and anti-biofouling performance. Herein, a water-stable and anti-biofouling ZIF-67/SAP0.45 composite hydrogel was reported by the sequential processes of electrostatic interactions between the oppositely charged polymer, ionic gelation, and template growth of ZIF-67 crystals. Entanglement of positively charged polyethyleneimine (PEI) and negatively charged sodium alginate (SA) polymer chains provided external porosities, anti-biofouling properties, and mechanical support for the hydrogels and further reduced the possibility of ZIF-67 aggregation. The neutral composite hydrogel possessed the least Nitzschia on the surface after 7 days contact, which endows the adsorbent with a high uranium uptake capacity of 2107.87 ± 41.64 μg g-1 at 1 mg L-1 uranium-containing seawater with 8.6 × 105 mL-1 Nitzschia. Additionally, this adsorbent showed water stability with an uranium uptake capacity of 232.88 ± 8.02 mg g-1 even after five adsorption-desorption cycles because of the excellent preparation method. Benefitting from the distinctive hierarchical structure and large accessible surface area, the resultant adsorbent achieved a high uranium capacity of 6.99 ± 0.26 mg g-1 in real seawater. This flexible and scalable approach made the MOF/SAP composite hydrogel a highly desirable uranium adsorbent.