Magneto-Responsive Shutter for On-Demand Droplet Manipulation.

Magnetically responsive structured surfaces enabling multifunctional droplet manipulation are of significant interest in both scientific and engineering research. To realize magnetic actuation, current strategies generally employ well-designed microarrays of high-aspect-ratio structure components (e.g., microcilia, micropillars, and microplates) with incorporated magnetism to allow reversible bending deformation driven by magnets. However, such magneto-responsive microarray surfaces suffer from highly restricted deformation range and poor control precision under magnetic field, restraining their droplet manipulation capability. Herein, a novel magneto-responsive shutter (MRS) design composed of arrayed microblades connected to a frame is developed for on-demand droplet manipulation. The microblades can perform two dynamical transformation operations, including reversible swing and rotation, and significantly, the transformation can be precisely controlled over a large rotation range with the highest rotation angle up to 3960°. Functionalized MRSs based on the above design, including Janus-MRS, superhydrophobic MRS (SHP-MRS) and lubricant infused slippery MRS (LIS-MRS), can realize a wide range of droplet manipulations, ranging from switchable wettability, directional droplet bounce, droplet distribution, and droplet merging, to continuous droplet transport along either straight or curved paths. MRS provides a new paradigm of using swing/rotation topographic transformation to replace conventional bending deformation for highly efficient and on-demand multimode droplet manipulation under magnetic actuation.