Transition-Metal Carbides as Hydrogen Evolution Reduction Electrocatalysts: Synthetic Methods and Optimization Strategies.

With the strengths of zero carbon emission and high gravimetric energy density, hydrogen energy is recognized as a primary choice for future energy supply. Electrochemical water splitting provides a promising strategy for effective and sustainable hydrogen production through renewable electricity, and one of the immediate challenges toward its large-scale application is the availability of low-cost and efficient electrocatalysts for the hydrogen evolution reaction (HER). Given the enormous efforts in the exploration of potential transition-metal carbide (TMC) electrocatalysts, this review aims to summarize the recent advances in synthetic methods and optimization strategies of TMC electrocatalysts. Additionally, the perspectives for the development of novel efficient TMC-based catalysts are also proposed.