Facile synthesis of sulfinate esters from aryl iodides via direct oxidation of thioesters.
Keisuke NakamuraYukiko KumagaiAkihiro KobayashiMinori SuzukiSuguru YoshidaPublished in: Organic & biomolecular chemistry (2023)
A practical method to synthesize sulfinate esters from aryl iodides is disclosed. Direct oxidation of thioesters prepared by copper-catalyzed C-S formation of aryl iodides realized the efficient synthesis of sulfinate esters. Due to the good accessibility of aryl iodides, a wide variety of sulfinate esters were prepared from easily available starting materials such as carboxylic acids and anilines.
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