Ruthenium-Catalyzed Intramolecular Double Hydroalkoxylation of Internal Alkynes.

Intramolecular double hydroalkoxylation of internal alkynes could be achieved using a Grubbs-type ruthenium carbene complex or its modified species to deliver a series of bridged- and spiroacetal derivatives in moderate to good yields. This study represents a new example of nonmetathetic reactions catalyzed by Grubbs-type ruthenium carbene complexes.