Nanoscale Interfacial Smoothing and Dissolution during Unconventional Reservoir Stimulation: Implications for Hydrocarbon Mobilization and Transport.

Hydraulic fracturing of low-permeability rocks significantly enhances hydrocarbon production from unconventional reservoirs. However, fluid transport through low-permeability rocks and the influence of geochemical transformations on pore networks are poorly constrained. Mineral reactivity during interactions with injected water may alter the physical nature of the rock, which may affect hydrocarbon mobility. To assess alterations to the rock, we have previously conducted a hydrothermal experiment that reacted cubed rock samples (1 cm3) with synthetic hydraulic fracturing fluid (HFF) to simulate physicochemical reactivity during hydraulic fracturing. Here, we analyze unreacted and reacted rocks by small-angle neutron scattering and high-pressure mercury intrusion to determine how the pore networks of unconventional reservoir rocks are influenced by the reaction with hydraulic fracturing injectates. Our results suggest that fluid-rock interactions exhibit a two-fold influence on hydrocarbon recovery, promoting both hydrocarbon mobilization and transport. Pore-matrix interfaces smooth via the removal of clay mineral surface asperities, reducing the available surface area for hydrocarbon adsorption by 12-75%. Additionally, HFF-induced dissolution creates new pores with diameters ranging from 800-1400 nm, increasing the permeability of the rocks by a factor of 5-10. These two consequences of mineral dissolution likely act in concert to release hydrocarbons from the host rock and facilitate transport through the rock during unconventional reservoir production.