Amine-modified polyionic liquid supports enhance the efficacy of PdNPs for the catalytic hydrogenation of CO 2 to formate.
Reece PatersonLuke E FahyElisabetta ArcaCasey DixonCorinne Y WillsHan YanAnthony GriffithsSean M CollinsKejun WuRichard A BourneThomas W ChamberlainJulian G KnightSimon DohertyPublished in: Chemical communications (Cambridge, England) (2023)
Palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid is a remarkably active catalyst for the hydrogenation of CO 2 to formate; the initial TOF of 500 h -1 is markedly higher than either unmodified catalyst or its benzylamine and N , N -dimethylaniline modified counterparts and is among the highest to be reported for a PdNP-based catalyst.