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A fluorinated alloy-type interfacial layer enabled by metal fluoride nanoparticle modification for stabilizing Li metal anodes.

Feng LiYi-Hong TanYi-Chen YinTian-Wen ZhangLei-Lei LuYong-Hui SongTe TianBao ShenZheng-Xin ZhuHong-Bin Yao
Published in: Chemical science (2019)
Using highly dispersed metal fluoride nanoparticles to construct a uniform fluorinated alloy type interfacial layer on the surface of Li metal anodes is realized by an ex situ solution chemical modification method. The fluorinated alloy-type interfacial layer can effectively inhibit the growth of undesirable Li dendrites while enhancing the performance of Li metal anodes.
Keyphrases
  • ion batteries
  • ionic liquid
  • molecular dynamics simulations
  • solid state
  • electron transfer