Performance evaluation of zero-valent iron nanoparticles (NZVI) for high-concentration H 2 S removal from biogas at different temperatures.

The removal performance of high-concentration H 2 S ( ca. 10 000 ppm) from simulated biogas by zero-valent iron nanoparticles (NZVI), with the majority of the particles in the size range of 60-150 nm, at different reaction temperatures (room temperature, 100 °C, 200 °C and 250 °C) were evaluated using a custom-designed quartz fixed-bed reactor. The results showed that the H 2 S removal capacities of NZVI were quite limited at room temperature and 100 °C, being 12.56 and 14.77 mg H 2 S gNZVI -1 , respectively. However, these values increased significantly to 391.02 (200 °C) and 488.95 (250 °C) mg H 2 S gNZVI -1 . Scanning electron microscopy analysis showed that the products of the NZVI-H 2 S reaction aggregated to form irregular polygonal-shaped structures. The main X-ray diffraction pattern peaks of the product matched well with troilite, and no pyrite was observed. The deconvolution of the X-ray photoelectron spectrometry peaks showed the presence of monosulphide (S 2- ) and disulphide (S 2 2- ) in the product, in which 36% of the sulphur existed as monosulphide and 64% as disulphide. It is proposed that the effective removal of hydrogen sulphide by NZVI at elevated temperatures can be attributed to the combination of nano-constituents, oxide shell and underlying Fe core to produce FeS similar to troilite and amorphous FeS 2 .