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Distinct relaxation mechanism at room temperature in metallic glass.

Yi-Tao SunRui ZhaoDa-Wei DingYan-Hui LiuHai-Yang BaiMao-Zhi LiWei-Hua Wang
Published in: Nature communications (2023)
How glasses relax at room temperature is still a great challenge for both experimental and simulation studies due to the extremely long relaxation time-scale. Here, by employing a modified molecular dynamics simulation technique, we extend the quantitative measurement of relaxation process of metallic glasses to room temperature. Both energy relaxation and dynamics, at low temperatures, follow a stretched exponential decay with a characteristic stretching exponent β = 3/7, which is distinct from that of supercooled liquid. Such aging dynamics originates from the release of energy, an intrinsic nature of out-of-equilibrium system, and manifests itself as the elimination of defects through localized atomic strains. This finding is also supported by long-time stress-relaxation experiments of various metallic glasses, confirming its validity and universality. Here, we show that the distinct relaxation mechanism can be regarded as a direct indicator of glass transition from a dynamic perspective.
Keyphrases
  • room temperature
  • ionic liquid
  • molecular dynamics simulations
  • single molecule
  • escherichia coli
  • high resolution
  • molecular dynamics