Copper-Catalyzed, Aerobic Synthesis of N H-Sulfonimidamides from Primary Sulfinamides and Secondary Amines.

N H-Sulfonimidamides are prepared by copper-catalyzed coupling of primary sulfinamides with secondary amines. Neither a ligand nor an additive is needed, and air is the terminal oxidant. The reactions occur at room temperature, show good functional group tolerance, and lead to products in good yields. A sulfanenitrile is proposed as an intermediate in this oxidative amination.