Avoiding water reservoir effects in ALD of functional complex alkali oxides by using O 3 as the oxygen source.
Henrik Hovde SønstebyVeronica A-L K KilliLinn M RykkjeJustin R BickfordEric G MartinRobert C HoffmanOla NilsenPublished in: Dalton transactions (Cambridge, England : 2003) (2022)
Toxic Pb-containing piezo-, pyro- and ferroelectrics continue to dominate the market even though they were banned from use in consumer products more than a decade ago. There is a strong need for sustainable alternatives, but the lack of facile synthesis routes for thin films exhibiting suitable functional properties have limited the transition from Pb workhorse materials like Pb(Zr,Ti)O 3 and Pb(Mg,Nb)O 3 - PbTiO 3 . Atomic layer deposition has proven capable of the deposition of possible successors, such as LiNbO 3 , (K,Na)NbO 3 and K(Ta,Nb)O 3 , albeit with limited control due to water reservoir effects resulting from the hygroscopicity of intermediate products. In this article, we show that replacing H 2 O with O 3 in the deposition of complex alkali oxides provides an alternative and much more controlled process. We exemplify this by deposition of crystalline K(Ta,Nb)O 3 with high compositional control and over a larger composition range than previously reported. This opens new doors to a simplified synthesis of polar functional lead-free alternatives.