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Carbon Nucleophile-Initiated Rauhut-Currier Reaction: An Atom-Economical Synthesis of Highly Functionalized Carbocycles.

Nicolas GigantEmmanuelle DrègeDelphine Joseph
Published in: The Journal of organic chemistry (2023)
A Rauhut-Currier reaction cascade is achieved in the presence of carbon nucleophiles under mild conditions. This original atom-economical transformation enables an efficient one-pot synthesis of densely substituted carbocycles from readily accessible substrates. The key promoter role of the cesium cation in the cascade process was demonstrated.
Keyphrases
  • electron transfer
  • molecular dynamics
  • dna methylation
  • gene expression
  • transcription factor
  • molecular docking
  • quantum dots
  • mass spectrometry