Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer.

Luciano BarluzziNadir JoriTianyi HeThayalan RajeshkumarRosario Scopelliti Laurent Maron Paul H Oyala Theodor Agapie Marinella Mazzanti

Published in: Chemical communications (Cambridge, England) (2022)

The reaction of a terminal Mo(II) nitride with a U(III) complex yields a heterodimetallic U-Mo nitride which is the first example of a transition metal-capped uranium nitride. The nitride is triply bonded to U(V) and singly bonded to Mo(0) and supports a U-Mo interaction. This compound shows reactivity toward CO oxidation.

Keyphrases

quantum dots
visible light
reduced graphene oxide
transition metal
molecular dynamics
gold nanoparticles