Oxygen reduction reaction activity of an iron phthalocyanine/graphene oxide nanocomposite.

Electrocatalysts with metal-nitrogen-carbon (M-N-C) sites have recently attracted much attention as potential catalysts for the oxygen reduction reaction (ORR), and a hybrid of iron phthalocyanine (FePc) and reduced graphene oxide (rGO) is one of the promising candidates. Herein, a FePc/GO nanocomposite was synthesized by electrostatic deposition on the electrode. The electrochemically reduced FePc/GO nanocomposite (ER(FePc/GO)) contained Fe 2+ centers in well reduced graphene sites without agglomeration. The ER(FePc/GO) exhibited high ORR activity with an ORR onset ( E onset ) and half-wave potential ( E 1/2 ) of 0.97 and 0.86 V, respectively. Furthermore, the ORR activity successfully improved by adding an electrolyte such as KCl or KNO 3 . The small H 2 O 2 yield of 2%, superior tolerance to methanol addition and high-durability indicate that the ER(FePc/GO) is a promising electrocatalyst. Theoretical studies, indicating that the presence of Cl - and NO 3 - ions lowered the conversion energy barrier, strongly supported the experimental results.