Light-Excited Ag-Doped TiO 2 -CoFe 2 O 4 Heterojunction Applied to Toluene Gas Detection.

(1) Background: Toluene gas is widely used in indoor decoration and industrial production, and it not only pollutes the environment but also poses serious health risks. (2) Methods: In this work, TiO 2 -CoFe 2 O 4 -Ag quaternary composite gas-sensing material was prepared using a hydrothermal method to detect toluene. (3) Results: The recombination of electron-hole pairs was suppressed, and the light absorption range was expanded after constructing a heterojunction and doping with Ag, according to ultraviolet-visible (UV-vis) diffuse reflectance spectra and photoluminescence spectroscopy. Moreover, in the detection range of toluene gas (3 ppm-50 ppm), the response value of TiO 2 -CoFe 2 O 4 -Ag increased from 2 to 15, which was much higher than that of TiO 2 -Ag (1.7) and CoFe 2 O 4 -Ag (1.7). In addition, the working temperature was reduced from 360 °C to 263 °C. Furthermore, its response/recovery time was 40 s/51 s, its limit of detection was as low as 10 ppb, and its response value to toluene gas was 3-7 times greater than that of other interfering gases under the same test conditions. In addition, the response value to 5 ppm toluene was increased from 3 to 5.5 with the UV wavelength of 395 nm-405 nm. (4) Conclusions: This is primarily due to charge flow caused by heterojunction construction, as well as metal sensitization and chemical sensitization of novel metal doping. This work is a good starting point for improving gas-sensing capabilities for the detection of toluene gas.