Violet-Blue Emitters Featuring Aggregation-Enhanced Emission Characteristics for Nondoped OLEDs with CIEy Smaller than 0.046.

High emission efficiency and finite molecular conjugation in the aggregate state are two desirable features in violet-blue emitters. Aggregation-induced emission luminogens (AIEgens) have emerged as promising luminescent materials that offer these features. Herein, we report the design and synthesis of a group of violet-blue tetraphenylbenzene-based AIEgens with photoluminescence quantum yields over 98% in their film states. When utilizing these AIEgens as nondoped emitting layers, the fabricated organic light-emitting diode exhibits a maximum external quantum efficiency of 4.34% with Commission Internationale de L'Eclairage (CIE) coordinates of (0.159, 0.035), which is amenable to the next-generation ultrahigh-definition television (UHDTV) display standard.