Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection.
Jinfang ZhangYuhang LiuJiaoyang FengLinpei GongMark G HumphreyChi ZhangPublished in: Inorganic chemistry (2019)
A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W2(μ3-S)6(μ4-S)2Cu8]4+, tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN- bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.
Keyphrases
- metal organic framework
- label free
- ionic liquid
- fluorescent probe
- molecularly imprinted
- living cells
- wastewater treatment
- quantum dots
- loop mediated isothermal amplification
- lymph node metastasis
- real time pcr
- squamous cell carcinoma
- water soluble
- energy transfer
- mass spectrometry
- sensitive detection
- light emitting
- simultaneous determination