Proton-Coupled Electron Transfer Induced by Near-Infrared Light.

A proton-coupled electron transfer reaction induced by near-infrared light (>710 nm) has been achieved using a dye that shows intense NIR absorption property and electron/proton-accepting abilities. The developed system generated long-lived radical species and showed high reversibility and robustness. Mechanistic investigations suggested that the rate-determining step of the reaction involves the proton transfer process.