Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol.

Michal AmanLibor Dostál Aleš RůŽičkaJiří TydlitátJens Beckmann Jan Turek Roman Jambor

Published in: Chemical communications (Cambridge, England) (2021)

A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(III) complex or as a κ2Sn,P-chelating ligand for Ru(II) compounds.

Keyphrases

energy transfer
ionic liquid
high intensity
alcohol consumption
highly efficient
molecular dynamics simulations
metal organic framework