Dual Polymer Complementarity Induced Truly Black Electrochromic Film and the Construction of Intelligent Eye-Protection Filters.

This work presents a new strategy to achieve a truly black electrochromic film and develop available intelligent eye-protection filters with "day mode" and "night mode", promising to minimize the harmful effects of light on eyes. The soluble red-to-transparent electrochromic polymer P1 was constructed using quinacridone as the basic unit and introduced dual-donor proDOT and DTC units with similar electron-donating capabilities. The beneficial broader absorption associated with the dual-donor in P1 results in ideal spectrum complementarity with P2 (cyan-to-transparent) in the visible region (380-780 nm). In addition to complementary colors, both polymers exhibit good compatibility with respect to electrochemical and electrochromic properties. Therefore, a P1/P2 film with a mass ratio of 1:1.5 for blending is preferred to obtain truly black color with fast switching time and good cyclic stability. Furthermore, an electrochromic device for intelligent eye-protection filters was designed and assembled with the P1/P2 film as the electrochromic layer and P3 featuring a yellow (antiblue ray)-to-dark gray color change as the ion storage layer. The assembled prototype electrochromic device demonstrated promising applications in intelligent day-night optical adjustment for eye-protection filters.