Functionalized MOF-Based Photocatalysts for CO 2 Reduction.

Metal-organic frameworks (MOFs) materials have become a research forefront in the field of photocatalytic CO 2 reduction attributed to their ultra-high specific surface area, adjustable structure, and abundant catalytic active sites. Particularly, MOFs can be facilely tuned to match CO 2 photoreduction by utilizing post-modification of metal nodes, functionalization of organic linkers, and combination with other active materials. Herein, the recent advances in the construction strategy of MOF-based photocatalysts materials for CO 2 reduction are highlighted. Some systematic modification strategies on MOF-based photocatalysts are also discussed, such as modification of metal sites and organic ligands, construction of heterojunction, introduction of single/dual-atom, and strain engineering. Finally, the future development directions of MOF-based photocatalysts in the field of CO 2 reduction are presented.