Pathway to a molecular calcium methyl.

Kyle G Pearce Samuel E Neale Claire L McMullinMary F MahonMichael S Hill

Published in: Chemical communications (Cambridge, England) (2024)

The dimeric β-diketiminato calcium hydride, [(BDI)CaH] 2 (BDI = HC{(Me)CN-2,6- i Pr 2 C 6 H 3 } 2 ), reacts with ZnMe 2 to afford the bimetallic calcium zincate complex, [(BDI)Ca(μ-CH 3 ) 2 Zn(μ-H)] 2 , which subsequently undergoes an intramolecular reaction to effect the formation of [(BDI)CaMe] 2 , a notable omission from the homologous series of β-diketiminato alkylcalcium derivatives.

Keyphrases

heavy metals
protein kinase
metal organic framework
quantum dots
electron transfer
structure activity relationship