Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation.

Ruth DorelPaula de MendozaPilar CallejaSergio PascualEsther González-CantalapiedraNoemí CabelloAntonio M Echavarren

Published in: European journal of organic chemistry (2016)

The synthesis of a new C3v -symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium-catalyzed intramolecular arylation of a syn-trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI-MS.

Keyphrases

mass spectrometry
multiple sclerosis
solar cells
ms ms
high speed
radiation induced