Interface Engineering Enables High-Performance Sb Anode for Sodium Storage.

Heterointerface engineering has been verified to be an effective approach to enhance the energy density of alkali-ion batteries by resolving inherent shortcomings of single materials. However, the rational construction of heterogeneous composite with abundant heterogeneous interfaces for sodium-ion batteries (SIBs) is still a significant challenge. Herein, inspired by density functional theory calculations, interface engineering can greatly decrease the energy bandgap and migration barrier of Na ions in Sb and Na 3 Sb phases, as well as enhance the mechanical properties. A porous heterointerface MOFC-Sb is fabricated by utilizing MOF-C as a support and buffer, exhibiting excellent electrochemical performances for sodium storage. The MOF-C-Sb anode with its rich heterointerface presents an improved electrochemical performance of 540.5 mAh g -1 after 100 cycles at 0.1 A g -1 , and 515.9 mAh g -1 at 1.6 A g -1 in term of sodium storage, efficiently resolving the serious volume expansion issues of metal Sb. These results indicate the structural superiority of heterointerface-engineered structure and afford valuable information for the rational design and construction of Sb-based anode materials for high-performance electrochemical energy storage.