A Simple and Strong Electron-Deficient 5,6-Dicyano[2,1,3]benzothiadiazole-Cored Donor-Acceptor-Donor Compound for Efficient Near Infrared Thermally Activated Delayed Fluorescence.

Despite the success of thermally activated delayed fluorescent (TADF) materials in steering the next generation of organic light-emitting diodes (OLEDs), effective near infrared (NIR) TADF emitters are still very rare. Here, we present a simple and extremely high electron-deficient compound, 5,6-dicyano[2,1,3]benzothiadiazole (CNBz), as a strong electron-accepting unit to develop a sufficiently strong donor-acceptor (D-A) interaction for NIR emission. End-capping with the electron-donating triphenylamine (TPA) unit created an effective D-A-D type system, giving rise to an efficient NIR TADF emissive molecule (λem =750 nm) with a very small ΔEST of 0.06 eV. The electroluminescent device using this NIR TADF emitter exhibited an excellent performance with a high maximum radiance of 10020 mW Sr-1  m-2 , a maximum EQE of 6.57% and a peak wavelength of 712 nm.