Dynamic Hydroxylation Enhances Hydrogen Atom Abstraction from Water for Nitrogen Fixation Revealed by Isotope Labeling in Situ Fourier-Transform Infrared Spectroscopy.

Employing water as a hydrogen source to participate in the hydrogen atom transfer (HAT) process is a low-cost and carbon-free process demonstrating great economic and environmental potential in catalysis. However, the low efficiency of hydrogen atom abstraction from water leads to slow kinetics of HAT for most hydrogenative reactions. Here, we prepared ultrathin Bi 4 O 5 Cl 2 nanosheets where the surface can be in situ reconstructed via hydroxylation under light illumination to facilitate the abstraction of hydrogen atoms from pure water for efficient nitrogen fixation. Consequently, the isotope labeling in situ Fourier-transform infrared spectroscopy (FT-IR) involving H 2 O and D 2 O has clearly revealed that the hydroxyl groups tend to be adsorbed on the chloride vacancy sites on the Bi 4 O 5 Cl 2 surface to form hydroxylated surfaces, where the hydroxylated photocatalyst surface enables partial dehydrogenation of water into H 2 O 2 , allowing the utilization of H atoms for efficient of N 2 hydrogenation via HAT steps. This work elucidates the in-depth reaction mechanism of hydrogen atom extraction from H 2 O molecules via the light-generated chloride vacancy to promote photocatalytic nitrogen fixation, ultimately enabling the inspiration and providing crucial rules for the design of important functional materials that can efficiently deliver active hydrogen for chemical synthesis.