First-principles structure prediction of two-dimensional HCN polymorphs obtained via formal molecular polymerization.

In the present study, ab initio evolutionary algorithms and heuristic approach were used to predict new two-dimensional (2D) hydrogen cyanide crystalline phases based on HCN and HNC molecular building blocks. Our research revealed thirty-seven 2D HCN and HNC structures within six topological families which contain N 1 , N 2 dimers, N 3 trimers, infinite poly-N motifs, or zigzag C-C chains. HSE06 functional calculations indicated that 2D 1 Pmn 2 1 HCN, 2 Pma 2 HCN, 3 P 2 1 2 1 2 HCN, and 6 Pbcm HNC are direct semiconductors with band gaps E g of 5.1, 4.2, 4.3, and 2.8 eV, respectively, and isovalent element substitutions (C by Ge/Si, and H by F) were performed to tune the electronic band gaps of the resulting 2D structures ( E g = 1.2-7.4 eV). Moreover, it has been found that the high in-plane Young's modulus (330.3-445.8 N m -1 ) and strong tolerance of direct band transitions ( E g = 1.2-5.3 eV) against the external biaxial strains in these four 2D HCN structures endow them with potential applications in photofunctional and flexible electronic devices. Finally, ab initio molecular dynamics simulations showed that at 50 GPa and 400 K, HCN molecules in a bulk I 4 mm hydrogen cyanide molecular crystal can extend to 2D HCN covalent nets.