Design Strategies for Single-Atom Iron Electrocatalysts toward Efficient Oxygen Reduction.

The oxygen reduction reaction (ORR) is a pivotal half-reaction for full cells and metal-air batteries. However, the intrinsic sluggish kinetics of the ORR inhibits the practical applications of these environmentally friendly energy-conversion devices. Therefore, highly efficient electrocatalysts with low cost are required to promote the ORR process. Carbon materials with single-atom Fe coordinated with N and C (Fe-N-C) stand out from various non-precious electrocatalysts, and great progress of both catalysts design and mechanism understanding has been achieved in the past. In this Perspective, we start with the recent advance in design strategies of active sites in Fe-N-C and emphasize the importance of spatial configuration and electron distribution. We discuss diverse Fe-N-C species as well as their corresponding properties. At last, we give our outlook for the future development of advanced Fe-N-C electrocatalysts.