Phosphorus-induced activation of Ir metallene for efficient acidic overall water electrolysis.

In this work, we synthesize P-doped Ir metallene (P-Ir metallene) with rich defects as a highly active bifunctional catalyst towards the hydrogen evolution reaction and oxygen evolution reaction, requiring overpotentials of 28 and 279 mV to drive 10 mA cm -2 in 0.5 M H 2 SO 4 , respectively. Moreover, P-Ir metallene exhibits excellent electrocatalytic performance for overall water splitting, producing hydrogen at 10 mA cm -2 with a low operation voltage of 1.508 V. This study proposes the incorporation of phosphorus into noble metals to improve the electrocatalytic performance for water splitting.