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Optical-Helicity-Dependent Orbital and Spin Dynamics in Two-Dimensional Ferromagnets.

Shuo LiRan WangThomas FrauenheimJunjie He
Published in: The journal of physical chemistry letters (2024)
Disentangling orbital (OAM) and spin (SAM) angular momenta in the ultrafast spin dynamics of two-dimensional (2D) ferromagnets on subfemtoseconds is a challenge in the field of ultrafast magnetism. Herein, we employed a non-collinear spin version of real-time time-dependent density functional theory to investigate the orbital and spin dynamics of the 2D ferromagnets Fe 3 GeTe 2 (FGT) induced by circularly polarized light. Our results show that the demagnetization of the Fe sublattice in FGT is accompanied by helicity-dependent precession of the OAM and SAM excited by circularly polarized lasers. We further identify that precession of the OAM and SAM in FGT is faster than demagnetization within a few femtoseconds. Remarkably, circularly polarized lasers can significantly induce a periodic transverse linear response of the OAM and SAM on very ultrafast time scales of ∼600 attoseconds. Our finding suggests a powerful new route for attosecond regimes of the angular momentum manipulation to coherently control helicity-dependent orbital and spin dynamics in 2D ferromagnets.
Keyphrases
  • density functional theory
  • molecular dynamics
  • room temperature
  • single molecule
  • transition metal
  • energy transfer
  • high resolution
  • electron transfer
  • ionic liquid
  • mass spectrometry
  • quantum dots