CoP Nanoparticle Confined in P, N Co-Doped Porous Carbon Anchored on P-Doped Carbonized Wood Fibers with Tailored Electronic Structure for Efficient Urea Electro-Oxidation.

Electronic structure optimization and architecture modulation are widely regarded as rational strategies to enhance the electrocatalysts catalytic performance. Herein, a hybridization of ZIF-67-derived CoP nanoparticles embedded in P, N co-doped carbon matrix (PNC) and anchored on P-doped carbonized wood fibers (PCWF) is constructed using a simple simultaneous phosphorization and carbonization strategy. Benefiting from the optimized surface/interface electronic structures, abundant exposed active sites, and outstanding conductivity, the CoP@PNC/PCWF can drive the urea oxidation reaction (UOR) with greater activity and better stability than most recently reported electrocatalysts, in which a potential as low as 1.32 V (vs reversible hydrogen electrode, RHE) is needed to reach 50 mA cm -2 and shows excellent durability. Furthermore, for overall urea splitting, using the CoP@PNC/PCWF electrocatalyst as the anode and commercial Pt/C supported on nickel foam as the cathode, an ultralow cell voltage of 1.50 V (vs RHE) is expected to achieve the 50 mA cm -2 and operate continuously for more than 50 h at 20 mA cm -2 . The reported strategy may shed light on the use of renewable resources to design and synthesize high-performance non-Ni-based phosphides UOR electrocatalysts for energy-saving H 2 production.