Recovering Marcus Theory Rates and Beyond without the Need for Decoherence Corrections: The Mapping Approach to Surface Hopping.

It is well-known that fewest-switches surface hopping (FSSH) fails to correctly capture the quadratic scaling of rate constants with diabatic coupling in the weak-coupling limit, as expected from Fermi's golden rule and Marcus theory. To address this deficiency, the most widely used approach is to introduce a "decoherence correction", which removes the inconsistency between the wave function coefficients and the active state. Here we investigate the behavior of a new nonadiabatic trajectory method, called the mapping approach to surface hopping (MASH), on systems that exhibit an incoherent rate behavior. Unlike FSSH, MASH hops between active surfaces deterministically and can never have an inconsistency between the wave function coefficients and the active state. We show that MASH not only can describe rates for intermediate and strong diabatic coupling but also can accurately reproduce the results of Marcus theory in the golden-rule limit, without the need for a decoherence correction. MASH is therefore a significant improvement over FSSH in the simulation of nonadiabatic reactions.