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Hydrophosphonodifluoromethylation of Alkenes via Thiyl-Radical/Photoredox Catalysis.

Wenhao HuangJingzhi ChenDaocheng HongWenxin ChenXu ChengYuxi TianGuigen Li
Published in: The Journal of organic chemistry (2018)
Visible-light-induced catalytic hydrophosphonodifluoromethylation of mono- and disubstituted alkenes using bromodifluoromethanephosphonate with a Hantzsch ester as the terminal reductant is reported. The combination of thiyl-radical catalysis with photoredox catalysis is important for achieving good chemoselectivity and high yields.
Keyphrases
  • visible light