π Back-Donation from a Beryllium Dibromide Fragment at the Expense of Its σ Strength.

It is common knowledge that metal-to-ligand π back-donation requires filled atomic orbitals at the metal center. However, we show through a combined experimental and theoretical approach that Be(II)→N-heterocyclic carbene (NHC) π back-donation is present in the two carbene adducts [(iPr)BeBr 2 ] ( 1 ) and [(iPr) 2 BeBr 2 ] ( 2 ) (iPr = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene). These complexes were characterized with NMR, IR, and Raman spectroscopy as well as with single-crystal X-ray diffractometry. The unusual bonding situation is understood from the results of energy decomposition analysis in combination with natural orbital for chemical valence and quantum theory of atoms-in-molecules analysis. The obtained findings shed light on the unusually high Be-C bond strength in carbene adducts to beryllium compounds and rationalize their geometry and reactivity.