NHC aluminum chemistry on the rise.

This perspective highlights recent developments of the use of N -heterocyclic carbenes (NHCs) and cyclic (alkyl)(amino)carbenes (cAACs) in alane and aluminum organyl chemistry. Especially in the last few years this flourishing research field led to some remarkable discoveries including various substitution patterns at the central aluminum atom, different oxidation states, neutral and charged compounds with varying coordination numbers and unique reactivities. Thereby NHCs play a vital role in the stabilization of these otherwise highly reactive compounds, which would not be realizable without the use of this intriguing class of ligands. Nevertheless, main group hydrides and especially NHC ligated alanes also tend to undergo NHC decomposition reactions, which are part of ongoing research and provide important information for NHC research in general.